Cyanide bridged tetranuclear complex with a novel terthiophene based ligand

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A novel Mn-containing conducting metallopolymer obtained by electropolymerization in aqueous solution of a tetranuclear oxo-bridged manganese complex.

The [Mn(4)(IV)O(5)(terpy)(4)(H(2)O)(2)](6+) complex shows great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electron transfer between dx(2)-y(2) orbitals of the metallic center and pπ orbital of the ligand.

متن کامل

A ferromagnetically coupled Fe42 cyanide-bridged nanocage

Self-assembly of artificial nanoscale units into superstructures is a prevalent topic in science. In biomimicry, scientists attempt to develop artificial self-assembled nanoarchitectures. However, despite extensive efforts, the preparation of nanoarchitectures with superior physical properties remains a challenge. For example, one of the major topics in the field of molecular magnetism is the d...

متن کامل

Ferro- and antiferromagnetic coupling in a chlorido-bridged, tetranuclear Cu(II) complex.

A bispidine-like ligand involving four pyridine-N and three aliphatic-N donor atoms forms a bimetallic species with CuCl2 in which all seven N-donors are bound and which aggregates in the crystal through double chloride-bridging to give a tetranuclear unit. The magnetism of this solid can be interpreted in terms of a relatively weak antiferromagnetic coupling between the two Cu(ii) centres of t...

متن کامل

Novel Thermally-Accessible Structural Distortion and Lattice Strain of a Chiral Cyanide-Bridged Cu (II)-Ni (II) Complex

We have investigated temperature dependence of crystal structure of a chiral cyanide-bridged bimetallic assembly of [CuL2][Ni(CN)4]·2H2O (1) (L = (1R, 2R)-diaminocyclohexane). Cell parameters and most of bond distances decreased on cooling for 1. However, only a long Cu-N bond of semi-coordination increases on cooling, which is the first example of negative thermal elongation of specific bond d...

متن کامل

Superparamagnetic bimetallic cyanide-bridged coordination nanoparticles with TB = 9 K.

Dispersible, nearly isolated 6 nm nanoparticles of the CsNiCr(CN)6 Prussian blue analogue coated with polyvinylpyrrolidone (PVP) show superparamagnetic behaviour with a relatively high blocking temperature TB = 9 K.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Polyhedron

سال: 2011

ISSN: 0277-5387

DOI: 10.1016/j.poly.2011.04.035